Assertion: Two mole of glucose contains 12.044 x 10²³ molecules of glucose
Reason: Total number of entities present in one mole of any substance is equal to 6.02 x 10²²
(a) both assertion and reason are true and the reason is the correct explanation of assertion
(b) both assertion and reason are true but reason is not the correct explanation of assertion
(c) assertion is true but reason is false
(d) both assertion and reason are false

(a)

both assertion and reason are true and the reason is the correct explanation of assertion

(b)

both assertion and reason are true but the reason is not the correct explanation of assertion

(c)

an assertion is true but reason is false

(d)

both assertion and reason are false

According to the Bohr Theory, which of the following transitions in the hydrogen atom will give rise to the least energetic photon?

(a)

n = 6 to n = 1

(b)

n = 5 to n = 4

(c)

n = 5 to n = 3

(d)

n = 6 to n = 5

Which of the following elements will have the highest electro negativity ____________

(a)

Chlorine

(b)

Nitrogen

(c)

Cesium

(d)

Fluorine

Ionic hydrides are formed by _____________

(a)

halogens

(b)

chalogens

(c)

inert gases

(d)

group one elements

RbO₂ is _____________

(a)

superoxide and paramagnetic

(b)

peroxide and diamagnetic

(c)

superoxide and diamagnetic

(d)

peroxide and paramagnetic

Gases deviate from ideal behavior at high pressure. Which of the following statement(s) is correct for non-ideality?

(a)

at high pressure the collision between the gas molecule become enormous

(b)

at high pressure the gas molecules move only in one direction

(c)

at high pressure, the volume of gas become insignificant

(d)

at high pressure the intermolecular interactions become significant

An ideal gas expands from the volume of 1 x 10^-3 m³ to 1 x 10^-2 m³ at 300 K against a constant pressure at 1 x 10⁵ Nm^-2. The work done is ______________

(a)

- 900 J

(b)

900 kJ

(c)

270 kJ

(d)

-900 kJ

K₁ and K₂ are the equilibrium constants for the reactions respectively.
\({ N }_{ 2 }(g)+{ O }_{ 2 }(g)\overset { { K }_{ 1 } }{ \rightleftharpoons } 2NO(g)\)
\(2NO(g)+{ O }_{ 2 }(g)\overset { { K }_{ 2 } }{ \rightleftharpoons } { 2NO }_{ 2 }(g)\)
What is the equilibrium constant for the reaction NO₂(g) ⇌ ½N₂(g) + O₂(g)

(a)

\({1\over \sqrt{K_1K_2}}\)

(b)

(K₁ = K₂)^1/2

(c)

\({1\over 2K_1K_2}\)

(d)

\(({1\over K_1K_2})^{3/2}\)

Stomach acid, a dilute solution of HCl can be neutralised by reaction with Aluminium hydroxide
Al (OH)₃ + 3HCl (aq) → AlCl₃ + 3 H₂O
How many millilitres of 0.1 M Al(OH)₃ solution are needed to neutralise 21 mL of 0.1 M HCl ?

(a)

14 mL

(b)

7 mL

(c)

21 mL

(d)

none of these

Assertion: Oxygen molecule is paramagnetic.
Reason: It has two unpaired electron in its bonding molecular orbital.
a) both assertion and reason are true and reason is the correct explanation of assertion
b) both assertion and reason are true but reason is not the correct explanation of assertion
c) assertion is true but reason is false
d) Both assertion and reason are false

(a)

both assertion and reason are true and reason is the correct explanation of assertion

(b)

both assertion and reason are true but reason is not the correct explanation of assertion

(c)

assertion is true but reason is false

(d)

Both assertion and reason are false

In the hydrocarbo \(\overset { 7 }{ { CH }_{ 3 } } -\overset { 6 }{ { CH }_{ 2 } } -\overset { 5 }{ CH } =\overset { 4 }{ CH } -\overset { 3 }{ { CH }_{ 2 } } -\overset { 2 }{ C } =\overset { 1 }{ CH } \) the state of hybridisation of carbon 1,2,3,4 and 7 are in the following sequence.

(a)

sp, sp, sp³, sp², sp³

(b)

sp², sp, sp³, sp², sp³

(c)

sp, sp, sp², sp, sp³

(d)

none of these

What is the hybridisation state of benzyl carbonium ion ?

(a)

sp²

(b)

spd²

(c)

sp³

(d)

sp²d

\({ C }_{ 2 }{ H }_{ 5 }Br+2Na\overset { dry\quad ether }{ \longrightarrow } { C }_{ 4 }{ H }_{ 10 }+2NaBr\) The above reaction is an example of which of the following

(a)

Reimer Tiemann reaction

(b)

Wurtz reaction

(c)

Aldol condensation

(d)

Hoffmann reaction

Of the following compounds, which has the highest boiling point?

(a)

n-Butyl chloride

(b)

Isobutyl chloride

(c)

t-Butyl chloride

(d)

n-propyl chloride

Identify the wrong statement in the following __________.

(a)

The clean water would have a BOD value of more than 5 ppm

(b)

Greenhouse effect is also called as Global warming

(c)

Minute solid particles in air is known as particulate pollutants

(d)

Biosphere is the protective blanket of gases surrounding the earth