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Organic Nitrogen Compounds 3 Mark Creative Question Paper With Answer Key

12th Standard

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Chemistry

Time : 01:30:00 Hrs
Total Marks : 45

    3 Marks

    15 x 3 = 45
  1. Write a note on acidic nature of nitro alkanes.

  2. How are nitro alkanes prepared for the following
    i) alkyl bromides
    ii) methane

  3. How will convert nitrobenzene to benzoic acid?

  4. Write a note on the basicity of amines.

  5. An Organic compound (A) with molecular formula C6H7N gives (B) with HNO2 / HCI at 273 K. The aqueous solution of (B) on heating gives compound (C) which gives violet colour with netural FeCI3. Identify the compounds (A), (B) and (C) and write the equations.

  6. Explain Levine and hauser acetylation.

  7. Outline the preparation of (a) para nitroaniline from aniline, (b) tri bromo benzene from tribromo aniline

  8. How can the following conversion be effected?
    i) Nitrobenzene to anisole
    ii) Chloro benzene to phenyl hydrazine
    iii)  Aniline to benzoic acid
    iv) Benzene diazonium chloride to ehtyl benzene.

  9. Aniline reacts with Br2/H2O to give a tribromo derivative. How would you convert aniline to get a monobromo derivate?

  10. How are the following compounds obtained from benzene diazonium chloride?
    (i) phenol
    (ii) ester
    (iii) p-hydroxy azo benzene

  11. Convert aniline to p-nitro aniline

  12. Write a note on structure of amine.

  13. Starting from the following reagents, how will your prepare ethanenitrile.
    i) CH3Br
    ii) CH3CONH2
    iii) CH3CH=NOH

  14. An organic compound 'A' on reduction gives compound 'B' which on reaction with trichloromethane and caustic potash forms 'C'. Compound 'C' on catalytic reduction given N-methyl benzenamine. Identify A, B and C and write the reactions involved.

  15. An organic compound (A) on reduction gives compound (B). (B) on treatment with CHCI3 and alcoholic KOH gives (C). (C) on catalytic reduction gives N - methyl aniline. Identify A, B, C and write its equation.

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