An alcohol (x) gives blue colour in victormayer’s test and 3.7g of X when treated with metallic sodium liberates 560 mL of hydrogen at 273 K and 1 atm pressure what will be the possible structure of X?

(a)

CH₃ CH (OH) CH₂CH₃

(b)

CH₃ – CH (OH) – CH₃

(c)

CH₃ – C (OH) – (CH₃)₂

(d)

CH₃- CH₂ –CH (OH) – CH₂ – CH₃

The X is _______.

(a)

(b)

(c)

(d)

None of these

Which one of the following is the strongest acid.

(a)

2 - nitrophenol

(b)

4 – chlorophenol

(c)

4– nitrophenol

(d)

3 – nitrophenol

Carbolic acid is _____.

(a)

Phenol

(b)

Picri cacid

(c)

benzoic acid

(d)

phenylacetic acid

Assertion: Phenol is more acidic than ethanol
Reason: Phenoxide ion is resonance stabilized
Codes:
a) both assertion and reason are true and reason is the correct explanation of assertion.
b) both assertion and reason are true but reason is not the correct explanation of assertion.
c) assertion is true but reason is false
d) both assertion and reason are false.

(a)

if both assertion and reason are true and reason is the correct explanation of assertion.

(b)

if both assertion and reason are true but reason is not the correct explanation of assertion.

(c)

assertion is true but reason is false

(d)

both assertion and reason are false.

HO CH₂ CH₂ – OH on heating with periodic acid gives  ______.

(a)

methanoic acid

(b)

Glyoxal

(c)

methanol

(d)

CO₂

The reactions
 is an example of  ______.

(a)

Wurtz reaction

(b)

cyclic reaction

(c)

Williamson reaction

(d)

Kolbe reactions

Among the following ethers which one will produce methyl alcohol on treatment with hot HI?

(a)

(H₃C)₃C-O-CH₃

(b)

(CH₃-)₂-CH-CH₂-O-CH₃

(c)

CH₃-(CH₂)₃-O-CH₃

(d)

CH₃-CH₂-\(\underset { \overset { | }{ { CH }_{ 3 } } }{ CH } \)-O-CH₃

On reacting with neutral ferric chloride, phenol gives  ______.

(a)

red colour

(b)

violet colour

(c)

dark green colour

(d)

no colouration.

Which among the following alkene on acid hydration will produce tertiary butyl alcohol?

(a)

\({ CH }_{ 3 }-\underset { \overset { | }{ { CH }_{ 3 } } }{ C } ={ CH }_{ 2 }\)

(b)

CH₃-CH=CH₂

(c)

\({ CH }_{ 3 }-\underset { \overset { || }{ { CH }_{ 2 } } }{ CH } \)

(d)

CH₃-CH₂-CH=CH-CH₃

Which one of the alcohol cannot be prepared by grignard reagent?

(a)

Methanol

(b)

ethanol

(c)

iso propyl alcohol

(d)

phenyl methanol

Which among the following reagent is not used to differentiate ethanol and phenol?

(a)

neutral FeCl₃

(b)

C₆H₅N₂CI

(c)

NaOH

(d)

anhy ZnCl₂

Glycol \(\overset { 773K }{ \longrightarrow } \) 'A'. Identify 'A' _______.

(a)

(b)

\(\overset { { CH }_{ 3 } }{ \underset { CHO }{ | } } \)

(c)

(d)

Which among the following sets of reactants will produce anisole?

(a)

HCHO, RMgX

(b)

(c)

C₆H₅ONa, CH₃Br

(d)

C₆H₅CH₃, CH₃CoCI

Which is soluble in H₂O?

(a)

Phenol

(b)

Alkanes

(c)

Alcohols

(d)

Alkenes

The ionization constant of phenol is higher than that of ethanol because ______.

(a)

phenoxide ion is bulkier than ethoxide

(b)

phenoxide ion is stronger base than ethoxide.

(c)

phenoxide ion is stablized through delocalisation.

(d)

phenoxide ion is less stable than ethoxide ion.

p-Nitrophenol is having lower pK_a value than phenol because ______.

(a)

phenol is more acidic than p-nitro phenol

(b)

anion of p-nitro phenol is more stabilised by resonance than that of phenol.

(c)

degree of ionisation of p-nitro phenol is less than that of phenol

(d)

anion of p-nitro phenol is less stable than that of phenol.

Ethylene diamine is converted to ethylene glycol using ______.

(a)

Na₂CO₃ solution

(b)

Nitrous acid

(c)

NaHCO₃ (aqueous)

(d)

Baeyer's reagent

When alcohols are converted to alkyl chlorides by thionyl chloride in presence of pyridine the intermediate formed is ______.

(a)

sulphonium ion

(b)

chlorosulphonic acid

(c)

alkyl chlorosulphite

(d)

chlorosulphite

Identify the major product in the given reaction

(a)

(b)

(c)

(d)