Which of the following compounds on reaction with methyl magnesium bromide will give tertiary alcohol.

(a)

benzaldehyde

(b)

propanoic acid

(c)

methyl propanoate

(d)

acetaldehyde

In the reaction sequence, Ethane \(\overset { HOCl }{ \longrightarrow } A\overset { x }{ \longrightarrow } \) ethan -1, 2 - diol. A and X respectively are ________.

(a)

Chloroethane and NaOH

(b)

ethanol and H₂SO₄

(c)

2 – chloroethan -1-ol and NaHCO₃

(d)

ethanol and H₂O

on treatment with Con H₂SO₄, predominately gives______.

(a)

(b)

(c)

(d)

Which one of the following will react with phenol to give salicyladehyde after hydrolysis.

(a)

Dichlo methane

(b)

trichloroethane

(c)

trichloro methane

(d)

CO₂

The correct IUPAC name of the compound

(a)

4 – chloro – 2,3 – dimethyl pentan – 1-ol

(b)

2,3 – dimethyl – 4- chloropentan -1-ol

(c)

2,3,4 – trimethyl – 4- chlorobutan -1-ol

(d)

4– chloro – 2,3,4 – trimethyl pentan – 1-ol

Assertion: Phenol is more reactive than benzene towards electrophilic substitution reaction
Reason: In the case of phenol, the intermediate arenium ion is more stabilized by resonance
Codes:
a) if both assertion and reason are true and reason is the correct explanation of assertion.
b) if both assertion and reason are true but reason is not the correct explanation of assertion.
c) assertion is true but reason is false
d) both assertion and reason are false.

(a)

if both assertion and reason are true and reason is the correct explanation of assertion.

(b)

if both assertion and reason are true but reason is not the correct explanation of assertion.

(c)

assertion is true but reason is false

(d)

both assertion and reason are false.

Which of the following compound can be used as antifreeze in automobile rediators?

(a)

methanol

(b)

ethanol

(c)

Neopentyl alcohol

(d)

ethan -1, 2-diol

One mole of an organic compound (A) with the formula C₃H₈O reacts completely with two moles of HI to form X and Y. When Y is boiled with aqueous alkali it forms Z. Z answers the iodoform test. The compound (A) is  ______.

(a)

propan – 2-ol

(b)

propan -1-ol

(c)

ethoxy ethane

(d)

methoxy ehane

Isoprophylbenzene on air oxidation in the presence of dilute acid gives ______.

(a)

C₆H₅COOH

(b)

C₆H₅COCH₃

(c)

C₆H₅COC₆H₅

(d)

C₆H₅- OH

Which among the following statement are correct with regard to alkyl halides?

(a)

Alkyl halides on heating with aq NaOH gives alcohols

(b)

1⁰ alkyl halides proceed by SN₂ mechanism

(c)

2⁰ and 3⁰ alkyl halides undergo substitution by SN₁ mechanism

(d)

all the above

Which one of the following alcohols on oxidation gives carboxylic acid with lesser number of carbon atoms?

(a)

(CH₃)₂-CH- CH₂OH

(b)

CH₃CH₂CHOHCH₃

(c)

CH₃-(CH₂)₃-CH₂OH

(d)

both (a) and (c)

Which one of the following would not react with cone. HCI and anhy. ZnCl₂ at room temperature?

(a)

(CH₃)₃COH

(b)

(CH₃)₂CHOH

(c)

\({ CH }_{ 3 }-{ CH }_{ 2 }-\underset { \overset { | }{ { CH }_{ 3 } } }{ CH } -OH\)

(d)

CH₃ - CH₂ - CH₂ - OH

The above reaction is called ______.

(a)

Gattermann reaction

(b)

Williamson ether synthesis

(c)

Swern's reaction

(d)

Riemer tiemann reaction

In the sequence of reactions Identify 'C'.

(a)

(b)

(c)

(d)

When phenol is distilled with zinc dust it gives______.

(a)

benzaldehyde

(b)

benzoic acid

(c)

toluene

(d)

benzene

1-Propanol and 2- propanol can be best distinguished by ______.

(a)

oxidation with KMnO₄ followed by reaction with Fehling solution

(b)

oxidation with acidic dichromate followed by reaction with Fehling solution

(c)

oxidation by heating with copper followed by reaction with Fehling solution

(d)

oxidation with concentrated H₂SO₄ followed by reaction with Pehling solution

The reactivity of alcohols with respect to oxidation decreases with ______.

(a)

increase in α - H

(b)

decrease in α - H

(c)

increase in β - H

(d)

decrease in β - H

The IUPAC name of 

(a)

2-methyl-2-propanol

(b)

2-methyl-l-butanol

(c)

2,3- dimethyl tributanol

(d)

2,3-dimethyl-2-butanol

Alcohols are isomeric with ______.

(a)

aldehyde

(b)

ketones

(c)

ethers

(d)

esters