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12th Standard English Medium Chemistry Subject Book Back 2 Mark Questions with Solution Part - II

12th Standard

    Reg.No. :
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Chemistry

Time : 01:00:00 Hrs
Total Marks : 30

    Part I

    15 x 2 = 30
  1. What are the differences between minerals and ores?

  2. Write a note on Fisher tropsch synthesis.

  3. Chalcogens belongs to p-block. Give reason.

  4. Why Gd3+ is colourless?

  5. Arrange the following in order of increasing molar conductivity
    (i) Mg[Cr(NH3)(Cl)5]
    (ii) Cr(NH3)5Cl]3[CoF6]2
    (iii) [Cr(NH3)3Cl3]

  6. Distinguish tetrahedral and octahedral voids.

  7. Explain the effect of catalyst on reaction rate with an example.

  8. When aqueous ammonia is added to CuSO4 solution, the solution turns deep blue due to the formation of tetra ammine copper (II) complex,\({ [Cu({ H }_{ 2 }O)_4] }_{ (aq) }^{ 2+ }+ 4{ NH }_{ 3 }(aq)\rightleftharpoons { [Cu{ ({ NH }_{ 3 }) }_{ 4 }] }_{ (aq) }^{ 2+ }\) among H2O and NH3 Which is stronger Lewis base.

  9. A conductivity cell has two platinum electrodes separated by a distance 1.5 cm and the cross sectional area of each electrode is 4.5 sq cm. Using this cell, the resistance of 0.5 N electrolytic solution was measured as 15 Ω. Find the specific conductance of the solution.

  10. The mechanism of Fridel crafts reaction is given below
    \({ C }_{ 6 }{ H }_{ 5 }+{ { CH }_{ 3 }Cl\overset { anhydrous\\ \quad { Alcl }_{ 3 } }{ \longrightarrow } }{ C }_{ 6 }{ H }_{ 5 }{ CH }_{ 3 }+HCl\)

  11. Can we use nucelophiles such as NH3,CH3- for the Nucleophilic substitution of alcohols

  12. Identify A, B and C
     

  13. Identify compounds A, B and C in the following sequence of reactions.
    i) \({ C }_{ 6 }{ H }_{ 5 }NO_{ 2 }\overset { Fe/HCL }{ \longrightarrow } A\overset { HN{ O }_{ 2 } }{ \underset { 273K }{ \longrightarrow } } B\overset { { C }_{ 6 }{ H }_{ 5 }OH }{ \longrightarrow } C\)
    ii) \({ C }_{ 6 }{ H }_{ 5 }N_{ 2 }cl\overset { CuCN }{ \longrightarrow } A\overset { H_{ 2 }O/H^{ + } }{ \longrightarrow } B\overset { NH_3 }{ \longrightarrow } C\)
    iii) \({ C }{ H }_{ 3 }{ C }{ H }_{ 2 }I\overset { NaCN}{ \longrightarrow } A\overset {OH^-}{ \underset {Partial hydrolysis}{ \longrightarrow } } B\overset {NaOH+Br_2 }{ \longrightarrow } C\)
    iv) \({ C }{ H }_{ 3 }NH_{ 2 }\overset { CH_3 Br }{ \longrightarrow } A\overset { CH_{ 3 }COCl}{ \longrightarrow } B\overset { B_2H_6 }{ \longrightarrow } C\)
    v) \({ C }_{ 6 }{ H }_{ 5 }NH_{ 2 }\overset { (CH_{ 3 }CO)_{ 2 }O }{ \underset { Pyridine }{ \longrightarrow } } A\overset { HNO_{ 3 } }{ \underset { H_{ 2 }SO_{ 4 },288K }{ \longrightarrow } } B\overset { { H }_{ 2 }O/{ H }^{ + } }{ \longrightarrow C } \)
    vi) 

    vii) \({ C }{ H }_{ 3 }CN_{ 2 }NC\overset { HgO }{ \longrightarrow } A\overset { H_{ 2 }O }{ \longrightarrow } B\overset { i) NaN{ O }_{ 2 }/HCL }{ \underset { ii){ H }_{ 2 }O }{ \longrightarrow } } \)

  14. Write a short note on peptide bond.

  15. What are food preservatives?

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