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Published on: 27/05/2021
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1.
A colourless liquid A contains H and O elements only. It decomposes slowly one exposure to light. It is stabilised by mixing urea to store in the presence of light.
(i) Suggest possible structure of A
(ii) Write chemical equations for its decomposition reaction in the light.
2.
An ionic hydride of an alkali metal has significant covalent character and is almost unreactive towards oxygen and chlorine. This is used in the synthesis of other useful hydrides. Write its reaction with \({ Al }_{ 2 }{ Cl }_{ 6 }\)
3.
What mass of hydrogen peroxide will be present in 2L of a 5M solution?
4.
Calculate the mass of oxygen which will be liberated by the decomposition of 200mL of this solution.
1.
Since, a colourless liquid A contains only H and O and decomposes slowly on exposure to light but is stabilised by additions of urea, therefore, liquid A may be hydrogen peroxide.
(ii) \(2{ H }_{ 2 }{ O }_{ 2 }\left( l \right) \underrightarrow { hv } 2{ H }_{ 2 }O\left( l \right) +{ O }_{ 2 }\left( g \right) \)
2.
It is LiH because it has significant covalent character due to the smallest alkali metal Li. LiH is very stable. It is almost unreactive towards oxygen and chlorine.
It reacts with \({ Al }_{ 2 }{ Cl }_{ 6 }\) to form lithium aluminium hydride.
\(8LiH+{ Al }_{ 2 }{ Cl }_{ 6 }\longrightarrow 2LiAl{ H }_{ 4 }+6LiCl\)
3.
Molar mass of \({ H }_{ 2 }{ O }_{ 2 }=34 \ gmol^{ -1 }\)
1L of 5M solution of \({ H }_{ 2 }O_{ 2 }\)will contain 34 x 5g \({ H }_{ 2 }O_{ 2 }\)
2L of 5M solution of \({ H }_{ 2 }O_{ 2 }\)will contain 34 x 5 x 2 = 340g \({ H }_{ 2 }O_{ 2 }\)
Mass of \({ H }_{ 2 }O_{ 2 }\)present in 2L of 5 molar solution = 340g
4.
0.2 L(or 200 mL) of 5M solution will contain
\(\frac { 340\times0.2 }{ 2 } =34g{ H }_{ 2 }{ O }_{ 2 }\)
\(\underset { 2\times 34=68g }{ { 2H }_{ 2 }O_{ 2 } } \rightarrow { 2H }_{ 2 }O+\underset { 2\times 16=32g }{ { O }_{ 2 } } \)
\(\because \ 68g \ { H }_{ 2 }O_{ 2 }\) on decomposition will give 32g\(O_{ 2 }\)
\(\therefore \ 34g \ { H }_{ 2 }O_{ 2 }\) on decomposition will give
\(\frac { 32\times 34 }{ 68 } =16g{ O }_{ 2 }\)
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