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1.
Identify the redox reaction out of the following reactions and identify the oxidising and reducing in them.
(i) 3HCl(aq) + HNO3(aq) \(\longrightarrow \) Cl2(g) +NOCl(g) + 2H2O(l)
(ii) \({ Hgcl }_{ 2 }(aq)+2KI(aq)\longrightarrow { HgI }_{ 2 }(s)+{ 2KCl(aq) }\)
(iii) Fe2O3 (s) + 3CO(g) \(\overset { \Delta }{ \longrightarrow } \)2Fe(s) +3CO2(g)
(iv) PCl3(l)+3H2O(l)⟶3HCl(aq)+H2PO3(aq)
(v) 4NH3(aq) + 3O2(g) \(\longrightarrow \) 2N2(g) + 6H2O(g)
2.
In Ostwald's process for the manufacture of nitric acid, the first step involves the oxidation of ammonia gas by oxygen gas to give nitric oxide gas and steam. What is the maximum weight of nitric oxide that can be obtained starting only with 10.0 g of ammonia and 20.0 g of oxygen?
1.
(a) Writing the On on each atom above its symbol, then
\(3\overset { +1 }{ H } \overset { -1 }{ Cl } (aq)+\overset { +1 }{ H } \overset { +5 }{ N } \overset { -2 }{ { O }_{ 3 } } (aq)\longrightarrow \overset { 0 }{ { Cl }_{ 2 }(g)+ } \overset { +3 }{ N } \overset { -2 }{ O } \overset { -1 }{ Cl(g)+ } \overset { +1 }{ { 2H }_{ 2 } } \overset { -2 }{ O } (l)\)
Here, the On of Cl increases from -1 in HCl to O in Cl2 , therefore, Cl- is oxidised and hence, HCl acts as the reducing agent. The ON of N decreases from +5 in HNO3 to +3 in NOCL, therefore, HNO3 acts as the oxidising agent. Thus this reaction is a redox reaction.
(b) Writing the ON of each atom above its symbol, we have,
\(\overset { +2 }{ Hg } \overset { -1 }{ { Cl }_{ 2 } } (aq)+\overset { +1 }{ 2K } \overset { -1 }{ I } (aq)\longrightarrow \overset { +2 }{ Hg } { \overset { -1 }{ I } }_{ 2 }(s)+2\overset { +1 }{ K } \overset { -1 }{ { Cl }^{ - }(aq) } \)
Here, the On of none of the atoms undergo a change, therefore, this reaction is not a redox reaction.
(c) \(\overset { +3 }{ { Fe }_{ 2 } } { \overset { -2 }{ O } }_{ 3 }(s)+3\overset { +2 }{ C } \overset { -2 }{ O } (g)\ \overset { \Delta }{ \longrightarrow } \ 2\overset { 0 }{ Fe } (s)+3\overset { +4 }{ C } \overset { -2 }{ { O }_{ 2 } } (g)\)
Here, On of decreases from +3 in Fe2O3 to 0 in Fe, therefore, Fe2O3 acts as an oxidising agent. Further, On of C increases from +2 in CO to +4 in CO2, therefore, CO acts as a reducing agent. Thus, this reaction is an example of redox reaction.
(d) Writing the ON of each atom above its symbol, then
\(\overset { +3 }{ P } { \overset { -1 }{ Cl } }_{ 3 }(l)+3\overset { +1 }{ { H }_{ 2 } } \overset { -2 }{ O } (l)\quad \longrightarrow \quad 3\overset { +1 }{ H } \overset { -1 }{ Cl } (aq)+\overset { +1 }{ { H }_{ 3 } } \overset { +3 }{ P } \overset { -2 }{ { O }_{ 3 } } (aq)\)
Here, On of none of the atoms undergo a change, therefore, this reaction is not a redox reaction.
(e) Writing the ON of each atom above its symbol, then
\(4\overset { -3 }{ N } \overset { +1 }{ { H }_{ 3 } } (aq)+3\overset { 0 }{ { O }_{ 2 } } (g)\quad \longrightarrow \quad 2\overset { 0 }{ { N }_{ 2 } } (g)+6\overset { +1 }{ { H }_{ 2 } } \overset { -2 }{ O } (l)\)
2.
The balanced equation for the reaction is
\(\underset { \overset { 4\quad \times \quad 17 }{ =68g } }{ 4{ NH }_{ 3 }(g) } +\underset { \overset { 5\quad \times \quad 32 }{ =160g } }{ { 5O }_{ 2 }(g) } \longrightarrow \underset { \overset { 4\quad \times \quad 30 }{ =120g } }{ { 4NO(g) } } +{ 6H }_{ 2 }O(g)\)
Here, 68 g of NH3 will react will 02 = 160 g
\(\therefore\) 10 g of NH3 will react with 02 = \(\frac { 160g }{ 68g } \) x 10g = 23.6g
But the amount of 02 which is actually available is 20.0 g which is less than the amount which is needed. Therefore, 02 is the limiting reagent and hence calculations must be based upon the amount of 02 taken and not on the amount of NH3 taken. From the equation
160 g of O2 produce NO = 120 g
\(\therefore\) 20g of O2 will produce NO = \(\frac { 120 }{ 160 } \times 20\) = 15g
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