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CBSE 12th Chemistry d- and f- Block Elements Important Questions And Answers Study Material - QB365 Set B

Published on: 07/03/2026
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Questions + Answers key
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2 Marks ( Answer any 5 questions )
1.
Why is nuclear density same for all nuclei?
2.
Out of alpha, beta and gamma radiations, which are affected by electric field and magnetic field?
3.
You are given two nuclei \(_{ 3 }{ { X }^{ 7 } }\) and \(_{ 3 }{ { Y }^{ 4 } }\) . Explain giving reasons, as to which one of the two nuclei is likely to be more stable?
4.
Write symbolically the nuclear \({ \beta }^{ + }\) decay process of \(_{ 6 }{ { C }^{ 11 } }\) . Is the decayed product X an isotope or isobar of \(_{ 6 }{ { C }^{ 11 } }\)?
Given the mass values of \((_{ 6 }{ { C }^{ 11 } })\)
11.011434 u and m(X) = 11.009305 u. Estimate the Q value in the process.
5.
Why do stable nuclei never have more protons than neutrons?
6.
The graph shown in the figure represents a plot of current versus voltage for a given semiconductor. Identify the region, if any, over which the semiconductor has a negative resistance.
7.
Draw the output waveform across the resistor in the given figure

8.
Assuming that the two diodes D1 and D2 used in the electric circuit as shown in the figure are ideal, find out the value of the current flowing through 1 \(\Omega \) resistor.

9.
What is the nuclear radius of 125Fe, if that of 27Al is 3.6 fm ?
Multiple Choice Question
10.
Hydrogen \(\left( _{ 1 }{ { H }^{ 1 } } \right) \), Deuterium \(\left( _{ 1 }{ { H }^{ 2 } } \right) \), singly ionized helium \({ \left( _{ 2 }{ { H }^{ 4 } } \right) }^{ + }\) and doubly ionized Lithium \({ \left( _{ 3 }{ { Li }^{ 7 } } \right) }^{ ++ }\) all have one electron around the nucleus. Consider an electron transition from n = 2 to n = 1. If wavelengths of emitted radiation are \({ \lambda }_{ 1 },{ \lambda }_{ 2 },{ \lambda }_{ 3 },{ \lambda }_{ 4 }\) respectively, then approximately which one of the following is correct?
\({ \lambda }_{ 1 }={ \lambda }_{ 2 }=4{ \lambda }_{ 3 }=9{ \lambda }_{ 4 }\)
\({ \lambda }_{ 1 }=2{ \lambda }_{ 2 }=3{ \lambda }_{ 3 }=4{ \lambda }_{ 4 }\)
\(4{ \lambda }_{ 1 }=2{ \lambda }_{ 2 }=2{ \lambda }_{ 3 }={ \lambda }_{ 4 }\)
\({ \lambda }_{ 1 }=2{ \lambda }_{ 2 }=2{ \lambda }_{ 3 }={ \lambda }_{ 4 }\)
11.
In the nuclear decay given below
\(_{ Z }{ { X }^{ A } }\longrightarrow _{ Z+1 }{ { Y }^{ A } }\longrightarrow _{ Z-1 }{ { B* }^{ A-4 } }\longrightarrow _{ Z-1 }{ { B }^{ A-4 } }\)
The particles emitted in the sequence are :
\(\alpha ,\ \beta ,\ \gamma \)
\(\beta ,\ \alpha ,\ \gamma \)
\(\gamma ,\ \beta ,\ \alpha \)
\(\beta ,\ \gamma ,\ \alpha \)
12.
In fusion reaction occurring in the sun,
hydrogen is converted into carbon
hydrogen and helium are converted into carbon and other heavier metals/elements
helium is converted into hydrogen
hydrogen is converted into helium
13.
A 220 V AC supply is connected between points A and B (figure). What will be the potential difference V across the capacitor?

220 V
110 V
0 V
\(220 \sqrt{2} \mathrm{~V}\)
14.
Which is reverse biased diode?




15.
The ratio of the nuclear densities of two nuclei having mass numbers 64 and 125 is
\(\frac{64}{125}\)
\(\frac{4}{5}\)
\(\frac{5}{4}\)
1
16.
The formation of depletion region in a p-n junction diode is due to
movement of dopant atoms
diffusion of the electrons and holes
drift of electrons only
drift of holes only
5 Marks
17.
(a) Explain with the help of a diagram, how a depletion layer and barrier potential are formed in a junction diode
(b) Draw a circuit diagram of full wave rectifier. Explain its working and draw input and output waveforms full wave rectifier. Explain its working and draw input and output waveforms
18.
(a) A germanium crystal is doped with antimony. With the help of energy-band diagram, explain how the conductivity of the doped crystal is affected.
(b) Briefly explain the two processes involved in the formation of a p-n junction.
(c) What will the effect of (I) forward biasing, and (II) reverse biasing be on the width of depletion layer in a p-n junction diode?
3 Marks
19.
(i) State Bohr's quantisation condition for defining stationary orbits. How does de-Broglie's hypothesis explain the stationary orbits?
(ii) Find the relation between the three wavelengths \(\lambda\)1, \(\lambda\)2 and \(\lambda\)3 from the energy level diagram shown below.

20.
From the relation R = R0A1/3, where R0 is a constant and A is the mass number of a nucleus, show that the nuclear matter density is nearly constant (i.e. independent of A).
21.
(i) Write the basic nuclear process involved in the emission of β+ in a symbolic form by a radioactive nucleus.
(ii) In the reactions given below:
\(\text { (a) }{ }_{6}^{11} \mathrm{C} \rightarrow{ }_{y}^{z} \mathrm{~B}+x+\mathrm{v}\)
\(\text { (b) }{ }_{6}^{12} \mathrm{C} \rightarrow{ }_{6}^{12} \mathrm{C}+{ }_{a}^{20} \mathrm{Ne}+{ }_{b}^{c} \mathrm{He}\)
Find the values of x, y and z and a, band c
22.
Briefly explain how a potential barrier is set up across a p-n junction as a result of diffusion and drift of the charge carriers.
23.
The figure shows a piece of pure semiconductor S in series with a variable resistor R and a Source of constant voltage V. Should the value of R be increased or decreased to keep the reading of the ammeter constant, when semiconductor S is heated? Justify your answer.

Or
The graph of potential barrier versus width of depletion region for an unbiased diode is shown in graph A. In comparison to A, graphs B and C are obtained after biasing the díode in different ways. Identify the type of biasing in B and C and justify your answer.

24.
(i) Differentiate between nuclear fission and nuclear fusion.
(ii) Deuterium undergoes fusion as per the reaction
\({ }_1^2 \mathrm{H}+{ }_1^2 \mathrm{H} \longrightarrow{ }_2^3 \mathrm{He}+{ }_0^1 n+3.27 \mathrm{MeV}\)
Find the duration for which an electric bulb of 500 W can be kept glowing by the fusion of 100 g of deuterium.
Case Study Questions
25.
A heavy nucleus breaks into comparatively lighter nuclei which are more stable compared to the original heavy nucleus. When a heavy nucleus like uranium is bombarded by slow moving neutrons, it splits into two parts releasing large amount of energy. The typical fission reaction of \({ }_{92} \mathrm{U}^{235}\).
\({ }_{92} \mathrm{U}^{235}+{ }_{0} n^{1} \rightarrow{ }_{56} \mathrm{Ba}^{141}+{ }_{36} \mathrm{Kr}^{92}+3{ }_{0} n^{1}+200 \mathrm{MeV}\)
The fission of 92U235approximately released 200 MeV of energy.
(i) If 200 MeV energy is released in the fission of a single nucleus of \({ }_{92}^{235} \mathrm{U}\),the fissions which are required to produce a power of 1kW is
| (a) 3.125 x 1013 | (b) 1.52 x 106 | (c) 3.125 x 1012 | (d) 3.125 x 1014 |
(ii) The release in energy in nuclear fission is consistent with the fact that uranium has
| (a) more mass per nucleon than either ofthe two fragments |
| (b) more mass per nucleon as the two fragment |
| (c) exactly the same mass per nucleon as the two fragments |
| (d) less mass per nucleon than either of two fragments. |
(iii) When 92U235undergoes fission, about 0.1% of the original mass is converted into energy. The energy released when 1 kg of 92U235undergoes fission is
| (a) 9 x 1011J | (b) 9 x 1013J | (c) 9 x 1015J | (d) 9 x 1018J |
(iv) A nuclear fission is said to be critical when multiplication factor or K
| (a) K= 1 | (b) K> 1 | (c) K< 1 | (d) K=0 |
(v) Einstein's mass-energy conversion relation E = mc2 is illustrated by
| (a) nuclear fission | (b) \(\beta\)-decay | (c) rocket propulsion | (d) steam engine |
26.
A pure semiconductor like Ge or Si, when doped with a small amount of suitable impurity, becomes an extrinsic semiconductor. In thermal equilibrium, the electron and hole concentration in it are related to the concentration of intrinsic charge carriers. A p-type or n-type semiconductor can be converted into a p-n junction by doping it with suitable impurity. Two processes, diffusion and drift take place during formation of a p-n junction. A semiconductor diode is basically a p-n junction with metallic contacts provided at the ends for the application of an external voltage. A p-n junction diode allows currents to pass only in one direction when it is forward biased. Due to this property, a diode is widely used to rectify alternating voltages in half-wave or full wave configuration.
(i) When Ge is doped with pentavalent impurity, the energy required to free the weakly bound electron from the dopant is about
| (a) | 0.001 eV | (b) | 0.01 eV |
| (c) | 0.72 eV | (d) | 1.1 eV |
(ii) At a given temperature, the number of intrinsic charge carriers in a semiconductor is 2.0 x 1010 cm-3. It is doped with pentavalent impurity atoms. As a result, the number of holes in it becomes 8 x 103 cm-3 The number of electrons in the semiconductor is
| (a) | 2 \(\times\) 1024 m-3 |
| (b) | 4 \(\times\) 1023 m-3 |
| (c) | 1 \(\times\) 1022 m-3 |
| (d) | 5 \(\times\) 1022 m-3 |
(iii) During the formation of a p-n junction
(a) electrons diffuse from p-region into n-region and holes diffuse from n-region into p-region.
(b) Both electrons and holes diffuse from n-region into p-region.
(c) electrons diffuse from n-region into p-region and holes diffuse from p-region into n-region.
(d) Both electrons and holes diffuse from p-region into n-region.
(Or)
(iii) Initially, during the formation of a p-n junction
(a) diffusion current is large and drift current is small.
(b) diffusion current is small and drift current is large.
(c) Both the diffusion and the drift currents are large.
(d) Both the diffusion andthe drift currents are small.
(iv) An AC voltage, V=0.5 sin (100 \(\pi\)t) V is applied, in turn, across a half- wave rectifier and a full wave rectifier. The frequency of the output voltage across them respectively will be
| (a) | 25 Hz, 50 Hz | (b) | 25 Hz, 100 Hz |
| (c) | 50 Hz, 50 Hz | (d) | 50 Hz, 100 Hz |
2 Marks ( Answer any 5 questions )
1.
This is because density \(=\frac{m a s s}{\text { volume }}\) and volume of nucleus varies directly as its mass number
2.
Both, alpha and beta radiations are affected by both, electric field and magnetic field.
3.
In case of \(_{ 3 }{ { X }^{ 7 } }\),
\(\frac { neutron\quad number }{ proton\quad number } =\frac { 7-3 }{ 3 } =1.33\)
In case of \(_{ 3 }{ { Y }^{ 4 } }\quad \)
\(\frac { neutron\quad number }{ proton\quad number } =\frac { 4-3 }{ 3 } =\frac { 1 }{ 3 } =0.33\)
For stability, this ratio has to be close to one.
Obviously, nucleus \(_{ 3 }{ { X }^{ 7 } }\) is more stable than the nucleus \(_{ 3 }{ { Y }^{ 4 } }\).
4.
\(_{ 6 }{ { C }^{ 11 } }\rightarrow _{ 5 }{ { X }^{ 11 } }+_{ 1 }{ { e }^{ 0 } }(i.e.,\quad { \beta }^{ + })+Q\)
Clearly, \(_{ 5 }{ { X }^{ 11 } }\) is an isobar of \(_{ 6 }{ { C }^{ 11 } }\).
Mass defect, \(\Delta m\) = 11.011434-(11.009305+0.000545)
= 0.001584 u
Q value of reaction \(=0.001584\times 931\ MeV\)
= 1.4747 MeV
5.
Because the protons are positively charged, so they repel each other. Since, this repulsion force is more, so that an excess of neutrons are required to reduce this repulsion.
6.
Resistance of a material can be found out by the slope of the curve V versus I. Part BC of the curve shows the negative resistance as with the increase in current, there is a decrease in voltage
7.
As, we know that the diode only works in forward biased, so the output is obtained only when positive input is given, so the output waveform is

8.
According to the question,

D2 is in reverse bias, so it acts as open circuit
\(\begin{aligned}
R_{\mathrm{eq}} & =2+1=3 \Omega
\end{aligned}\)
\(\begin{aligned}
I & =\frac{V}{R_{\mathrm{eq}}}=\frac{6}{3}=2 \mathrm{~A}
\end{aligned}\)
9.
Given, nuclear radius of 27Al, r1 = 3.6 fm
Nuclear radius of 125Fe, r2 = ?
A1 = 27, A2 = 125
The nuclear radius is given by
\(R=R_0 A^{\frac{1}{3}} \Rightarrow R \propto A^{\frac{1}{3}} \)
\(\therefore\) \(\frac{R_2}{R_1}=\left(\frac{A_2}{A_1}\right)^{\frac{1}{3}}=\left(\frac{125}{27}\right)^{\frac{1}{3}}=\frac{5}{3}\)
\(\therefore\)\(R_2=\frac{5}{3} R_1=\frac{5}{3}\)x 3.6 = 6 fm
\(\therefore\) R2 = 6 fm
Multiple Choice Question
10.
(a)
\({ \lambda }_{ 1 }={ \lambda }_{ 2 }=4{ \lambda }_{ 3 }=9{ \lambda }_{ 4 }\)
11.
(b)
\(\beta ,\ \alpha ,\ \gamma \)
12.
(d)
hydrogen is converted into helium
13.
(d)
\(220 \sqrt{2} \mathrm{~V}\)
14.
(b)

15.
(d)
1
16.
(b)
diffusion of the electrons and holes
5 Marks
17.
.png)
(a) Due to the diffusion of electrons and the holes, from their majority zone to minority zone, a layer of positive and negative space charge region on either side on the junction is formed. This is called the depletion region.
The loss of electrons, from n-region and gain of electrons by the p-region, causes a difference of potential across the junction. This tends to prevent the movement of charge carriers across the junction and is, therefore, termed as barrier potential.
.png)
For positive half cycle of input ac, one of the two diodes gets forward biased and conducts and output current is obtained across the load RL, For negative half cycle of input ac, the other diode
gets forward biased and thus output current is obtained due to it. Therefore, output is obtained for both the cycles of input ac.

.png)
18.
3 Marks
19.
(i) According to Bohr's principle, electrons revolve in a stationary orbit of which energy and momentum are fixed. The momentum of electrons in the fixed orbit is given by \(\frac { nh }{ 2\pi } \) (where n = the number of orbits). According to de-Broglie's hypothesis, the electron is associated with wave character. Hence, a circular orbit can be taken to be a stationary energy state only. if it contains an integral number of de-Broglie wavelengths, i.e., 2\(\pi\)r = n\(\lambda\)
(ii) According to question,

\({ E }_{ B }-{ E }_{ C }=\frac { hc }{ { \lambda }_{ 1 } } \quad \quad ...(i)\)
\({ E }_{ A }-{ E }_{ B }=\frac { hc }{ { \lambda }_{ 2 } } \quad \quad ...(ii)\)
\({ E }_{ C }-{ E }_{ A }=\frac { -hc }{ { \lambda }_{ 3 } } \quad ...(iii)\)
On adding Eqs. (i), (ii) and (iii), we get
EB - EC + EA - EB + EC - EA
\(=hc\left( \frac { 1 }{ { \lambda }_{ 1 } } +\frac { 1 }{ { \lambda }_{ 2 } } -\frac { 1 }{ { \lambda }_{ 3 } } \right) \)
\(\frac { 1 }{ { \lambda }_{ 3 } } =\frac { 1 }{ { \lambda }_{ 1 } } +\frac { 1 }{ { \lambda }_{ 2 } } \Rightarrow { \lambda }_{ 3 }=\frac { { { \lambda } }_{ 1 }{ \lambda }_{ 2 } }{ { \lambda }_{ 1 }+{ \lambda }_{ 2 } } \)
20.
We have the expression for nuclear radius as:
R = R0A1/3
Where,
R0 = Constant.
A = Mass number of the nucleus
Nuclear matter density, \(\rho \ =\frac{Mass\ of\ the\ nucles}{Volume\ of\ the\ nucles}\)
Let m be the average mass of the nucleus.
Hence, mass of the nucleus = mA
\(\therefore \rho=m \frac{A}{\frac{4}{3} \pi R^{3}}=\frac{3 \mathrm{~mA}}{4 \pi\left(R_{0} A^{\frac{1}{3}}\right)^{3}}=\frac{3 m A}{4 \pi R_{0}^{3} A}=\frac{3 \mathrm{~m}}{4 \pi R_{0}^{3}}\)
Hence, the nuclear matter density is independent of A. It is nearly constant.
21.
(i) The basic nuclear process involved in the emission of β+ during radioactivity is given by
\({ }_{Z}^{A} X \longrightarrow{ }_{Z-1}^{A} Y+\beta^{+}+v\)
(ii) (a) According to question
\({ }_{6}^{11} \mathrm{C} \longrightarrow{ }_{y}^{z} \mathrm{~B}+x+\mathrm{v}\)
For β+-decay,
\(z X^{A} \longrightarrow z_{-1} Y^{A}+\beta^{+}+v\)
On comparing Eqs. (i) and (ii), we get
\(y=5, z=11 \text { and } x=\beta^{+}\)
\(\text { (b) }{ }_{6}^{12} \mathrm{C}+{ }_{6}^{12} \mathrm{C} \longrightarrow{ }_{a}^{20} \mathrm{Ne}+{ }_{b}^{c} \mathrm{He}\)
Helium have 4 mass number and 2 charge number. So reaction will be
\({ }_{6}^{12} \mathrm{C}+{ }_{6}^{12} \mathrm{C} \longrightarrow{ }_{10}^{20} \mathrm{Ne}+{ }_{2}^{4} \mathrm{He}\)
On comparing Eqs. (i) and (ii), we get
a = 10, b = 2 and c = 4
22.

The accumulation of negative charges in the p-region and positive charges in the M-region set up a potential difference across the junction. This acts as a barrier and is called potential barrier.
23.
The value of resistance (R) should be increased to keep the reading of ammeter constant, as with the increase in the temperature of a semiconductor, its resistance decreases and current tends to increase.
Or
For graph B,
As the potential barrier in graph B is higher with respect to potential barrier in graph 4, i.e. potential barrier in graph B is increased. So, it is the case of reverse biased condition.
For graph C,
As the potential barrier in graph C is decreased with respect to potential barrier in graph A. So, the graph C is the case of forward biased condition.
24.
(a) Fission is the process of separating two heavy, unstable atomic nuclei into two lighter nuclei, also releasing energy, but less than with fusion. Fusion is where two light atomic nuclei unite and release energy.
| Nuclear Fission | Nuclear Fusion |
| When the nucleus of an atom splits into lighter nuclei through a nuclear reaction the process is termed nuclear fission. | Nuclear fusion is a reaction through which two or more light nuclei collide with each other to form a heavier nucleus. |
| When each atom split, a tremendous amount of energy is released. | The energy released during nuclear fusion is several times greater than the energy released during nuclear fusion. |
| Fission reactions do not occur in nature naturally. | Fusion reactions occur in stars and the sun. |
| Little energy is needed to split an atom in a fission reaction. | High energy is needed to bring fuse two or more atoms together in a fusion reaction. |
| Atomic bomb works on the principle of nuclear fission. | Hydrogen bomb works on the principle of a nuclear fusion bomb. |
(b) Number of atoms in 100g deuterium, \(\frac{100}{2} \times 6.023 \times 10^{-23}\)
Energy Released- \(\frac{3.27}{2} \times 1.6 \times 10^{-13} \mathrm{~J}\)
Time required t = Total energy(E) / Power of lamp (P)
= 500 \(\times\) 60 \(\times\) 60 \(\times\) 24 \(\times\) 365
t = 1.5768 \(\times\) 1010 years.
Case Study Questions
25.
(i) (a) : Let the number of fissions per second be n. Energy released per second
\(=n \times 200 \mathrm{MeV}=n \times 200 \times 1.6 \times 10^{-13} \mathrm{~J}\)
Energy required per second = power x time
\(=1 \mathrm{~kW} \times 1 \mathrm{~s}=1000 \mathrm{~J}\)
\(\therefore \quad n \times 200 \times 1.6 \times 10^{-13}=1000\)
\(\text { or } \quad n=\frac{1000}{3.2 \times 10^{-11}}=\frac{10}{3.2} \times 10^{13}=3.125 \times 10^{13}\)
(ii) (a)
(iii) (b): As only 0.1% of the original mass is converted into energy, hence out of 1 kg mass 1 g is converted into energy.
\(\therefore\) Energy released during fission, \(E=\Delta m c^{2}\)
\(=1 \mathrm{~g} \times\left(3 \times 10^{8} \mathrm{~m} \mathrm{~s}^{-1}\right)^{2}=10^{-3} \times 9 \times 10^{16} \mathrm{~J}=9 \times 10^{13} \mathrm{~J}\)
(iv) (a)
(v) (a)
26.
(i) (c) The energy required to free the weakly bound electron from the dopant is about 0.7 eV.
(ii) (d) Here,
Number of intrinsic charge carriers,
\(n_i=2.0 \times 10^{10} \mathrm{~cm}^{-3}\)
Number of holes, nh = 8 \(\times\) 103 cm-3
We know that,
\(\begin{aligned} n_e n_h & =n_i^2 \end{aligned}\)
\(\Rightarrow\) \(\begin{aligned} n_e & =\frac{n_i^2}{n_h}=\frac{\left(2.0 \times 10^{10}\right)^2}{8 \times 10^3} \\ \end{aligned}\)
\(\begin{aligned} =\frac{4.0 \times 10^{20}}{8 \times 10^3}=0.5 \times 10^{17} \mathrm{~cm}^{-3} \end{aligned}\)
= 5 \(\times\) 1016 cm-3
ne = 5 \(\times\)10+22 m-3
(iii) (c) In the p-section, holes are the majority carriers; while in n-section,the majority carriers are electrons. Due to the high concentration of different types of charge carriers in the two section, holes from p-region diffuse into n-region and electrons from n-region diffuse into p-region.
Or
(iii) (d) Initially, during the formation of p-n junction, diffusion of majority charge carriers take place from p-side to n-side which constitute the diffusion current. Thus, diffusion current is large and the drift current is small.
(iv) (d) Given,
AC voltage V = 0.5 sin (100 \(\pi\)t) V
Here, V0 = 0.5
\(\begin{aligned} \omega & =100 \pi \end{aligned}\)
\(\begin{aligned} 2 \pi f & =100 \pi \end{aligned}\)
\(\Rightarrow\) f = 50 Hz
The frequency of the output voltage across half- wave rectifier is 50Hz and across full wave rectifier is 100Hz.
12th Standard CBSE Syllabus & Materials
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